Difference between revisions of "User:Tohline/PGE/FirstLawOfThermodynamics"

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Following the detailed discussion of the laws of thermodynamics that can be found, for example in Chapter I of [<b>[[User:Tohline/Appendix/References#C67|<font color="red">C67</font>]]</b>] we know that, "<font color="#007700">for an infinitesimal quasi-statical change of state,</font>" the change <math>~dQ</math> in the total heat content <math>~Q</math> of a fluid element is given by, what we will label as the,
Following the detailed discussion of the laws of thermodynamics that can be found, for example in Chapter I of [<b>[[User:Tohline/Appendix/References#C67|<font color="red">C67</font>]]</b>] we know that, "<font color="#007700">for an infinitesimal quasi-statical change of state,</font>" the change <math>~dQ</math> in the total heat content <math>~Q</math> of a fluid element is given by, what we will label as,


<div align="center">
<div align="center">
<span id="Standard Form"><font color="#770000">'''Standard Form'''</font></span><br />
<span id="FormA"><font color="#770000">'''Form A'''</font></span><br />
of the First Law of Thermodyamics
of the First Law of Thermodyamics


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[<b>[[User:Tohline/Appendix/References#C67|<font color="red">C67</font>]]</b>], Chapter II, Eq. (2)
[<b>[[User:Tohline/Appendix/References#C67|<font color="red">C67</font>]]</b>], Chapter II, Eq. (2)
</div>
</div>
where, {{ User:Tohline/Math/VAR_SpecificInternalEnergy01 }} is the specific internal energy, {{ User:Tohline/Math/VAR_Pressure01 }} is the pressure, and {{ User:Tohline/Math/VAR_SpecificVolume01 }}<math>~= 1/</math>{{ User:Tohline/Math/VAR_Density01 }} is the specific volume of the fluid element.  Now, if it is understood that the specified changes are occurring over a certain interval of time <math>~dt</math>, then from this expression we can directly derive what will henceforth be referred to as,
where, {{ User:Tohline/Math/VAR_SpecificInternalEnergy01 }} is the specific internal energy, {{ User:Tohline/Math/VAR_Pressure01 }} is the pressure, and {{ User:Tohline/Math/VAR_SpecificVolume01 }}<math>~= 1/</math>{{ User:Tohline/Math/VAR_Density01 }} is the specific volume of the fluid element.  Generally, the change in the total heat content can be rewritten in terms of the gas temperature, {{ User:Tohline/Math/VAR_Temperature01 }}, and the specific entropy of the fluid, {{ User:Tohline/Math/VAR_SpecificEntropy01 }}, via the expression,
<div align="center">
<table border="0" cellpadding="5" align="center">
 
<tr>
  <td align="right">
<math>~dQ</math>
  </td>
  <td align="center">
<math>~=</math>
  </td>
  <td align="left">
<math>~T ds \, .</math>
  </td>
</tr>
</table>
[<b>[[User:Tohline/Appendix/References#C67|<font color="red">C67</font>]]</b>], Chapter II, Eq. (44)
</div>
 
 
If, in addition, it is understood that the specified changes are occurring over a certain interval of time <math>~dt</math>, then from this pair of expressions we derive what will henceforth be referred to as the,
 
<div align="center">
<span id="Standard Form"><font color="#770000">'''Standard Form'''</font></span><br />
of the First Law of Thermodyamics
 
{{ User:Tohline/Math/EQ_FirstLaw01 }}
 
[<b>[[User:Tohline/Appendix/References#C67|<font color="red">C67</font>]]</b>], Chapter II, Eq. (2)
</div>


&nbsp;<br />
&nbsp;<br />
{{LSU_HBook_footer}}
{{LSU_HBook_footer}}

Revision as of 21:16, 23 October 2018

First Law of Thermodynamics

Whitworth's (1981) Isothermal Free-Energy Surface
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Following the detailed discussion of the laws of thermodynamics that can be found, for example in Chapter I of [C67] we know that, "for an infinitesimal quasi-statical change of state," the change <math>~dQ</math> in the total heat content <math>~Q</math> of a fluid element is given by, what we will label as,

Form A
of the First Law of Thermodyamics

<math>~dQ</math>

<math>~=</math>

<math>~ d\epsilon + PdV \, , </math>

[C67], Chapter II, Eq. (2)

where, <math>~\epsilon</math> is the specific internal energy, <math>~P</math> is the pressure, and <math>~V</math><math>~= 1/</math><math>~\rho</math> is the specific volume of the fluid element. Generally, the change in the total heat content can be rewritten in terms of the gas temperature, <math>~T</math>, and the specific entropy of the fluid, <math>~s</math>, via the expression,

<math>~dQ</math>

<math>~=</math>

<math>~T ds \, .</math>

[C67], Chapter II, Eq. (44)


If, in addition, it is understood that the specified changes are occurring over a certain interval of time <math>~dt</math>, then from this pair of expressions we derive what will henceforth be referred to as the,

Standard Form
of the First Law of Thermodyamics

LSU Key.png

<math>T \frac{ds}{dt} = \frac{d\epsilon}{dt} + P \frac{d}{dt} \biggl(\frac{1}{\rho}\biggr)</math>

[C67], Chapter II, Eq. (2)

 

Whitworth's (1981) Isothermal Free-Energy Surface

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